A Study of Effect of Concentration on Efficiency of dye-Sensitized Solar cells (DSSC) Based on ZnS

Authors

  • Haider Mushina Obeed Department of Medical Physics, College of Applied Medical Science, Shatrah University, Iraq

Keywords:

Concentration, Efficiency, N3-Ruthenium, ZnS, DSSC

Abstract

In this work, the effect of concentration on efficiency can be studied based on theoretical approach for N3 dye contact ZnS semiconductor based on dye sensitized solar cells DSSCs  .  The impact current density based on transition energy, , atomic density, length of charge, concentration as well as  polarity of both N3  -ZnS  system on the electronic transport process. The chemical Ethanol solvents using a polar media with N3 dye –ZnS semiconductor system. The current density  component is evaluated relative to transition energy, driving energy, potential and coupling parameters. The strength coupling and concentration on the current density behavior can be discussion in N3-ZnS devices, that's reflected in the electronic transport results.The current density results reveal the behaviour of current density has been  strongly affected by the concentration, it determine the efficiency of N3-ZnS devices. The electron transfer ability has been limited current density due to transition energy, driving force and potential. The efficiency, influenced by the carrier concentration increases of   N3-ZnS devices ,it plays a significantly in the increases  current density as well as limited the electrical properties of N3-ZnS devices. Specifically, the overlapping coupling between N3  dye and  ZnS was influenced on the electronic current density.In general, the increases in concentration from  to  is favorable and increases efficiency from 4.09  to 4.448  ,it suggests that N3 dye a suitable contact for  ZnS -based DSSCs devices.

Downloads

Download data is not yet available.

References

M. Singh and R. K. Kanaparthi, “Theoretical exploration of 1,3-Indanedione as electron acceptor-cum-anchoring group for designing sensitizers towards DSSC applications,” Solar Energy, vol. 237, pp. 456–469, 2022.

P. Liu, B. Xu, K. M. Karlsson, J. Zhang, N. Vlachopoulos, G. Boschloo, L. Sun, and L. Kloo, “The combination of a new organic D–π–A dye with different organic hole-transport materials for efficient solid-state dye-sensitized solar cells,” Journal of Materials Chemistry A, vol. 3, pp. 4420–4427, 2015.

S. H. Aung, Y. Hao, T. Z. Oo, and G. Boschloo, “2-(4-Butoxyphenyl)-N-hydroxyacetamide: An efficient preadsorber for dye-sensitized solar cells,” ACS Omega, vol. 2, pp. 1820–1825, 2017.

M. M. Theint, H. E. Maung, S. H. Aung, N. W. Lwin, and T. Z. Oo, “Effect of photo anode modification on charge transport recombination and efficiency of dye sensitized solar cells using synthetic organic dyes,” Journal of Materials Science and Engineering A, vol. 10, no. 1–2, pp. 30–36, 2020.

H. J. M. Al-Agealy and M. A. Hassooni, “IBNALHAITHAM J (FOR PURE & APPL SCI),” vol. 24, no. 3, 2011.

H. J. M. Al-Agealy and M. Z. Fadhil, “Estimation of the electric properties of Al/Cv system,” Journal of University of Babylon for Pure and Applied Sciences, vol. 28, no. 1, pp. 184–194, 2020.

S. G. Abuabara, L. G. C. Rego, and V. S. Batista, “Influence of thermal fluctuations on interfacial electron transfer in functionalized TiO2 semiconductors,” Journal of the American Chemical Society, vol. 127, pp. 18234–18242, 2005.

A. V. Müller, W. M. Wierzba, M. N. Pastorelli, and A. S. Polo, “Interfacial electron transfer in dye-sensitized TiO2 devices for solar energy conversion,” Journal of the Brazilian Chemical Society, vol. 32, no. 9, pp. 1711–1738, 2021.

H. J. M. Al-Agealy, K. H. Harbbi, M. A. Hassooni, and R. I. Noori, “Theoretical study of charge transfer in StyrylThiaziloQuinoxaline dyes STQ-1, STQ-2, and STQ-3 in organic media system,” Baghdad Science Journal, vol. 10, no. 4, 2013.

H. J. M. Al-Agealy and H. H. D. Al Janeri, “Investigation the flow charge rate at InAs/D149 and ZnO/D149 system using theoretical quantum model,” AIP Conference Proceedings, vol. 2123, p. 020055, 2019, doi: 10.1063/1.5116982.

H. J. M. Al-Agealy and J. S. H. Al-Hakany, “Theoretical calculations of rate constant of electron transfer across N3/TiO2 sensitized dye interface solar cell,” Ibn Al-Haitham Journal for Pure and Applied Science, vol. 25, no. 2, pp. 160–169, 2012.

H. J. M. Al-Agealy, B. Alshafaay, M. A. Hassooni, A. M. Ashwiekh, A. K. Sadoon, R. H. Majeed, R. Q. Ghadhban, and S. H. Mahdi, “Theoretical discussion of electron transport rate constant at TCNQ/Ge and TiO2 system,” Journal of Physics: Conference Series, vol. 1003, p. 012122, 2018.

M. Hollerer, D. Lüftner, P. Hurdax, T. Ules, S. Soubatch, F. S. Tautz, G. Koller, P. Puschnig, M. Sterrer, and M. G. Ramsey, “Charge transfer and orbital level alignment at inorganic/organic interfaces: The role of dielectric interlayers,” ACS Nano, vol. 11, no. 6, pp. 6252–6260, 2017.

H. J. M. Al-Agealy and M. Z. Fadhil, “Estimation of the electric properties of Al/Cv system,” Journal of University of Babylon for Pure and Applied Sciences, vol. 28, no. 1, 2020.

X. Wang, H. Huang, B. Liang, Z. Liu, D. Chen, and G. Shen, “ZnS nanostructures: Synthesis, properties, and applications,” Critical Reviews in Solid State and Materials Sciences, vol. 38, pp. 57–90, 2013.

I.-D. Simandan, F. Sava, A.-T. Buruiana, I. Burducea, N. Becherescu, C. Mihai, A. Velea, and A.-C. Galca, “The effect of the deposition method on the structural and optical properties of ZnS thin films,” Coatings, vol. 11, p. 1064, 2021.

H. J. M. Al-Agealy and R. I. N. Al-Obaidi, “Charge transfer at semiconductor/liquid interfaces,” Ibn Al-Haitham Journal for Pure and Applied Science, vol. 22, no. 2, 2009.

T. S. Al Maadhde, M. H. Jumali, H. J. M. Al-Agealy, F. A. Razak, and C. C. Yap, “An investigation of the fill factor and efficiency of molecular semiconductor solar cells,” Materials Science Forum, vol. 1039, pp. 373–381, 2021.

S. S. Al-Obaidi, H. J. M. Al-Agealy, and S. R. Abbas, “Theoretical evaluation of flow electronic rate at Au/TFB interface,” Journal of Physics: Conference Series, vol. 1879, p. 032096, 2021, doi: 10.1088/1742-6596/1879/3/032096.

H. M. Obeed and H. J. M. Al-Agealy, “Investigation and studied of charge transfer processes at HATNA and HATNA-Cl6 molecules contact with Cu metal,” AIP Conference Proceedings, vol. 2292, pp. 040010-1–040010-8, 2020.

W. J. Royea, A. M. Fajardo, and N. S. Lewis, “Fermi golden rule approach to evaluating outer-sphere electron-transfer rate constants at semiconductor/liquid interfaces,” Journal of Physical Chemistry B, vol. 101, pp. 11152–11159, 1997.

A. K., F. R. A., and M. H. Ahmadi, “Generation and combination of the solar cells: A current model review,” Energy Science & Engineering, pp. 1–18, 2019.

H. J. M. Al-Agealy and J. S. H. Al-Hakany, “Theoretical calculations of rate constant of electron transfer across N3/TiO2 sensitized dye interface solar cell,” Ibn Al-Haitham Journal for Pure and Applied Science, vol. 25, no. 2, 2012.

H. J. Al-Agealy and T. S. Al Maudhady, “Influence of the polarity function on the probability of transition rate constant (sec−1) at metal/molecule in nano scale devices,” International Journal of Application or Innovation in Engineering & Management, vol. 3, no. 5, 2014.

H. J. M. Al-Agealy, A. K. Saadon, M. A. Hassooni, and R. Q. Ghadhban, “Investigating of charge transfer in Cu/F8 using donor-acceptor model due quantum transition,” Journal of Physics: Conference Series, vol. 1879, 2021.

S. M. Sze, K. K. Ng, and Y.-M. Lee, Physics of Semiconductor Devices. Hoboken, NJ, USA: John Wiley & Sons, 2018.

W. M. Haynes, Ed., CRC Handbook of Chemistry and Physics. Boca Raton, FL, USA: CRC Press, 2014.

P. Patnaik, Handbook of Inorganic Chemicals. New York, NY, USA: McGraw-Hill, 2003.

Downloads

Published

2026-06-01

How to Cite

Haider Mushina Obeed. (2026). A Study of Effect of Concentration on Efficiency of dye-Sensitized Solar cells (DSSC) Based on ZnS . Central Asian Journal of Theoretical and Applied Science, 7(3), 115–122. Retrieved from https://www.cajotas.casjournal.org/index.php/CAJOTAS/article/view/1699

Issue

Section

Articles